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Title : Effect of Process Parameters on Removal and Recovery of Cd(II) and Cu(II) from Electroplating Wastewater by Fixed-bed Column of Nano-dimensional Titanium (IV) Oxide Agglomerates
Author(s) : Sushanta Debnath, Kriveshini Pillay, Uday Chand Ghosh, Arjun Maity
Author affiliation : 1 Department of Chemistry and Biochemistry, Presidency University, 86/1 College Street, Kolkata 700073, India
2 Department of Applied Chemistry, University of Johannesburg, Doornfontein, Johannesburg, South Africa
3 National Centre for Nano-structured Materials, Council of Scientific and Industrial Research, Pretoria, South Africa
Corresponding author img Corresponding author at : Corresponding author img  

Removal performances of Cd(II) and Cu(II) from water was investigated using agglomerated nanoparticle of hydrous titanium(IV) oxide (NTO) packed fixed bed. The parameters varied were the bed depth, flow rate and feed solution concentrations. Comparison of breakthrough volumes indicated that at pH 5.0, the removal performances of Cd(II) was better than Cu(II) and the maximum adsorption capacity are 44.12 and 41.96 mg.g-1 for Cd(II) and Cu(II), respectively. The breakthrough data described the Thomas, Yoon and the Bed Depth Service Time (BDST) models better than the Adams–Bohart model. The Thomas model column capacity (q0) for the Cd(II) was greater than the Cu(II) at any condition. The breakthrough time (tb) of BDST model increased with increasing bed depth of NTO columns. A fixed bed of NTO column treated the Cd(II) and Cu(II) contaminated industrial wastewater successfully. The metals were recovered as their oxides from the column regeneration effluent solution.

Key words:Removal; Cadmium(II); Copper(II); Fixed bed column; Titanium(IV) oxide; Wastewater

Cite it:
Sushanta Debnath, Kriveshini Pillay, Uday Chand Ghosh, Arjun Maity, Effect of Process Parameters on Removal and Recovery of Cd(II) and Cu(II) from Electroplating Wastewater by Fixed-bed Column of Nano-dimensional Titanium (IV) Oxide Agglomerates, Advances in Industrial Engineering and Management, Vol.3, No.3, 2014, pp.63-78, doi: 10.7508/AIEM-V3-N3-63-78

Full Text : PDF(size: 1.12 MB, pp.63-78, Download times:417)

DOI : 10.7508/AIEM-V3-N3-63-78

[1] Raichur, A. M., Jyoti, B. M. 2001. Adsorption of fluoride onto mixed rare earth oxides, Separ. Purif. Technol. 24, 121-127.
[2] Luxton, T.P., Eick, M.J., Scheckel, K.G. 2008. Arsenate adsorption on ruthenium oxides: A spectroscopic and kinetic investigation. J. Colloid Interf. Sci. 325, 23-30.
[3] Mohapatra, M., Rout, K., Mohapatra, B.K., Anand, S. 2009. Sorption behavior of PbII and CdII on iron ore slime and characterization of metal ion loaded sorbent, J. Hazard. Mater. 166, 1506-1513.
[4] Effect of operating conditions on the removal of Pb2+ by microporous titanosilicate ETS-10 in a fixed-bed column, J. Colloid Interf. Sci. 305, 218-225.
[5] Chowdhury, A.N., Rahim, A., Ferdosi, Y.J., Azam, Md., Hossain, M.M. 2010. Cobalt-nickel mixed oxide surface: A promising adsorbent for the removal of PR dye from water, Appl. Surf. Sci. 256, 3718-3724.
[6] Adak, A., Pal, A., Bandyopadhyay, M. 2006. Removal of phenol from water environment by surfactant-modified alumina through adsolubilization, Colloid Surf. A. 277, 63-68.
[7] Tripathy, S.S., Bersillon, J.L., Gopal, K. 2006. Removal of fluoride from drinking water by adsorption onto alum-impregnated activated alumina, Separ. Purif. Technol. 50, 310-317.
[8] Kundu, S., Gupta, A.K. 2006. Arsenic adsorption onto iron oxide-coated cement IOCC: Regression analysis of equilibrium data with several isotherm models and their optimization, Chem. Eng. J. 122, 93-106.
[9] Suksabye, P., Thiravetyan, P., Nakbanpote, W. 2008. Column study of chromiumVI adsorption from electroplating industry by coconut coir pith, J. Hazard. Mater. 160, 56-62.
[10] Kundu, S., Gupta, A.K. 2005. Analysis and modeling of fixed bed column operations on AsV removal by adsorption onto iron oxide-coated cement IOCC, J. Colloid Interf. Sci. 290, 52-60.
[11] Sperlich, A., Werner, A., Genz, A., Amy, G., Worch, E., Jekel, M. 2005. Breakthrough behavior of granular ferric hydroxide GFH fixed-bed adsorption filters: modeling and experimental approaches, Water Res. 39, 1190-1198.
[12] Hristovski, K., Baumgardner, A., Westerhoff, P. 2007. Selecting metal oxide nanomaterials for arsenic removal in fixed bed columns: From nanopowders to aggregated nanoparticle media, J. Hazard. Mater. 147, 265-274.
[13] Debnath, S., Ghosh, U.C. 2009. Nanostructured hydrous titaniumIV oxide: Synthesis, characterization and NiII adsorption behavior. Chem. Eng. J. 152, 480-491.
[13] Debnath, S., Ghosh, U.C. 2011. Equilibrium modeling of single and binary adsorption of CdII and CuII onto agglomerated nano structured titaniumIV oxide, Desalination 273, 330-342.
[14] Manna, B. R., Dasgupta, M., Ghosh, U. C. 2004. Crystalline hydrous titanium IV oxide CHTO: An arsenic III scavenger from natural water, J. Water Supply Res. Technol.-Aqua 53, 483-495.
[15] Debnath, S., Ghosh, U.C. 2008. Kinetics, isotherm and thermodynamics for CrIII and CrVI adsorption from aqueous solutions by crystalline hydrous titanium oxide, J. Chem. Thermodyn. 40, 67-77.
[16] Sadaf, S., Bhatti, H.N. 2014. Batch and fixed bed column studies for the removal of Indosol Yellow BG dye by peanut husk, J. Taiwan Inst Chem. Eng. 45, 541- 553.
[17] Amin, M., Bhatti, H.N., Sadaf, S. 2013. Bioremediation of Zirconium from Aqueous Solution by Coriolus versicolor : Process Optimization J. Chem. Soc. Pak. 35, 692-698.
[18] Sadaf, S., Bhatti, H.N., Ali, S., Rehman, K. 2014. Removal of Indosol Turquoise FBL dye from aqueous solution by bagasse, a low cost agricultural waste: batch and column study, Desalination Water Treat. 52, 184–198.
[19] Debnath, S., Roy, N.R., Ghosh, U.C. 2011. Characterization of agglomerated nanosized titaniumIV oxide prepared by two pathways and their performance toward CuII adsorption, Inter. J. Green Nanotechnol. 3, 271-280.
[20] Thomas, H.C. 1944. Heterogenous ion exchange in a flowing system, J. Amer. Chem. Soc. 66, 1664-1666.
[21] Bohart, G., Adams, E.N. 1920. Some aspects of the behaviour of charcoal with respect to chlorine, J. Amer. Chem. Soc. 42, 523.
[22] Lehman, M., Zouboulis, A. I., Matis, K.A. 2001. Modelling the sorption of metals from aqueous solutions on goethite fixed-beds, Environ. Pollut. 113, 121-128.
[23] Muraleedharan, T. R., Philip, L., Iyengar, L. 1994. Application studies of biosorption for monazite processing industry effluents, Biores. Technol. 49, 179-186.
[24] Yoon, Y.H., Nelson, J.H. 1984. Application of gas adsorption kinetics. 1. A theoretical model for respirator cartridge service time, Amer. Industr. Hyg. Assoc. J. 45, 516.
[25] Hutchins, R.A. 1973. New Method Simplifies Design of Activated Carbon System, Chem. Eng. 80, 138.
[26] Sarin, V., Singh, T.S., Pant, K.K. 2006. Thermodynamic and breakthrough column studies for the selective sorption of chromium from industrial effluent on activated eucalyptus bark, Biores. Technol. 97, 1986-1993.
[27] Medvidovic, N. V., Peric, J., Trgo, M. 2006. Column performance in lead removal from aqueous solutions by fixed bed of natural zeolite-clinoptilolite, Separ. Purif. Technol. 49, 237-244.
[28] Aksu, Z., Gonen, F. 2006. Binary biosorption of phenol and chromiumVI onto immobilized activated sludge in a packed bed: Prediction of kinetic parameters and breakthrough curves, Separ. Purif. Technol. 49, 205-216.
[29] Hamdaoui, O. 2006. Dynamic sorption of methylene blue by cedar sawdust and crushed brick in fixed bed columns, J. Hazard. Mater. 138, 293-303.
[31] Juang, R.S., Kao, H.C., Chen, W. 2006. Column removal of NiII from synthetic electroplating wastewater using a strong-acid resin. Separ. Purif. Technol. 49, 36-42.
[32] Malkoc, E., Nuhoglu. Y., Abali, Y. 2006. CrVI adsorption by waste acorn of Quercus ithaburensis in fixed beds: Prediction of breakthrough curves, Chem. Eng. J. 119, 61-68.
[33] Ko, D.C.K., Porter, J.F., Mckay, G. 2000. Optimised correlations for the fixed-bed adsorption of metal ions on bone char, Chem. Eng. Sci. 55, 5819- 5829.
[34] Li, C., Champgne, P. 2009. Fixed-bed column study for the removal of cadmium II and nickel II ions from aqueous solutions using peat and mollusk shells, J. Hazard. Mater. 171, 872-878.
[35 ] Jain, M., Garg, V.K., Kadirvelu, K. 2013. CadmiumII sorption and desorption in a fixed bed column using sunflower waste carbon calcium–alginate beads, Biores. Technol, 129, 242-248.
[36] Sankararamakrishnan, N., Kumar, P., Chauhan, V.S. 2008. Modeling fixed bed column for cadmium removal from electroplating wastewater, Separ. Purif. Technol. 63, 213-219.
[37] Rao, K.S., Anand, S., Venkateswarlu, P., 2011. Modeling the kinetics of CdII adsorption on Syzygium cumini leaf powder in a fixed bed mini column, J. Indust. Eng. Chem. 17, 174-181.
[38] Hamdaoui, O. 2009. Removal of copperII from aqueous phase by Purolite C100-MB cation exchange resin in fixed bed columns: Modeling, J. Hazard. Mater. 161, 737-746.
[39] Luo, X., Liu, F., Deng, Z., Lin, X. 2011. Removal of copperII from aqueous solution in fixed-bed column by carboxylic acid functionalized deacetylated konjac glucomannan, Carbohydrate Polym. 86, 753-759.
[40] Hasfalina, C.M., Maryam, R.Z., Luqman, C.A., Rashid, M. 2012. Adsorption of Copper II From Aqueous Medium In Fixed-Bed Column By Kenaf Fibres, APCBEE Procedia 3, 255–263.
[41] Han, R., Lou, Z., Zhao, X., Xu, Y., Xu, F., Li, Y., Wang, Y. 2009. Characterization and properties of iron oxide-coated zeolite as adsorbent for removal of copperII from solution in fixed bed column, Chem. Eng. J. 149, 123-131.
[42] Yin, C.Y., Aroua, M.K., Ashri, W.M., Daud, W. 2009. Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon, Chem. Eng. J. 148, 8-14.

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